TB Research

Asymmetric trehalose analogues to probe disaccharide processing pathways in mycobacteria

Parker HL, Tomás RMF, Furze CM, Guy CS, Fullam E

Organic & biomolecular chemistry · 2020-05

Abstract

The uptake and metabolism of the disaccharide trehalose by Mycobacterium tuberculosis is essential for the virulence of this pathogen. Here we describe the chemoenzymatic synthesis of new azido-functionalised asymmetric trehalose probes that resist degradation by mycobacterial enzymes and are used to probe trehalose processing pathways in mycobacteria.

MeSH terms

  • Mycobacterium tuberculosis
  • Trehalose
  • Disaccharides
  • Microscopy, Fluorescence
  • Carbohydrate Conformation